Abstract and keywords
Abstract (English):
In the article, within the framework of the conformational approach, the problem of averaging the square of vector quantities of complex polymers is presented. This approach is based on determining the average values of the square of the dipole moment for the µ-th monomeric unit of the chain, which is a unique parameter of the supramolecular structure of the polymer, depending on the product of the rotation matrices. A generalization of the matrix method of averaging the product of several tensor quantities over possible conformations within the entire macromolecule is considered.

Keywords:
conformational approach, rotary-isomeric model, macromolecule, monomeric unit
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References

1. Bartenev, G.M. Fizika polimerov / G.M. Bartenev, S.Ya. Frenkel'. - Leningrad: Himiya, 1990. - 432 s.

2. Birshteyn, T.M. Konformacii makromolekul / T.M. Birshteyn, O.B.Pticyn. - Moskva: Nauka, 1964. - 392s.

3. Papulov, Yu.G. Konformacionnye raschety / Yu.G. Papulov, P.G. Halatur. - Kalinin: Izd-vo Kalininskogo universiteta,1980. - 88 s.

4. Birshteyn, T.M. Konformacii makromolekul i vnutrimolekulyarnye konformacionnye perehody / T.M. Birshteyn // Vysokomolekulyarnye soedineniya. SeriyaA. - 2019. - T. 61. - №6. - S. 542-552.

5. Conformation of block cool gomer macromolecules containing a discotic block/ N.D. Merekalova, A.S. Merekalov, O.A.Otmakhova, R.V.Talroze //Polymer Science. Series A. - 2008. -T. 50. -№ 1. -S. 84-90.

6. Conformations Amphiphlite Polyelectrolyte Stars with Didblock Copolymer Arms /A.A. Polotsky, T.M.Birshtein, O.V.Borisov, M.Daond // Macromolecules. -2013.-V.46.-№ 22.- P.8999-9012.

7. Konformaciizhidkokristallicheskihpolimerovsmezogenamivosnovnoycepi / T.M. Birshteyn, B.Z. Volchek, A.A. Merkur'eva, S.V. Shilov // Vysokomolekulyarnyesoedineniya.- 1993. - T. 35. - № 11. - S. 1765-1771.

8. Bischoff, R. Polysiloxanes in macromolecular architecture / R.Bischoff, S.E.Gray // Progress in Polymer Science.- 1999.- V.24.- №2.- P.185-219.

9. Stimuli-Responsive Brushes with Active Minority Components: Monte Carlo Study and Analytical Theory / S. Qi, F. Schmid, L.I. Klushin [et al]// Macromolecules. - 2015. - V. 48. - № 11. - P. 3775-3787.

10. Kline, S. Structural evolution during micelle polymerization / S. Kline //J. Appl. Cryst. - 2000. - V. 33. - P. 618-622.

11. Vozniknovenieneodnorodnogotemperaturnogo polya pri temperaturnom skanirovanii kristallizuyuschihsya polimerov / N.Yu. Evsikova, N.S. Kamalova, V.V. Postnikov, N.N.Matveev//Fundamental'nye problemy radioelektronnogo priborostroeniya. - 2007. - T.7. - №3. -S. 99-102.

12. Raznost' potencialov, voznikayuschaya v prirodnoy drevesine pod deystviem neodnorodnyh temperaturnyh poley / N.Yu. Evsikova, N.S. Kamalova, V.V. Postnikov [i dr.] // Vestnik fiziko-matematicheskogo fakul'teta Eleckogo gosudarstvennogo universiteta im. I.A. Bunina. - Elec: Eleckiy gosudarstvennyy universitet im. I.A. Bunina, 2006. - S. 218-221.

13. Konformacionnaya model' operatora dipol'nogo momenta makromolekuly kristallizuyuschegosya polimera v neodnorodnom temperaturnom pole / N.N. Matveev, V.I. Lisicyn, V.V. Saushkin, N.S. Kamalova // Plasticheskie massy. - 2021. - № 3-4. - S. 22-23.

14. Vliyanie konformaciy gibkocepnyh polimerov na izmenenie polyarizovannosti v neodnorodnom temperaturnom pole / N.N. Matveev, V.I. Lisicyn, V.V. Saushkin, N.S. Kamalova // Plasticheskie massy. - 2021. - № 1-2. - S. 44-45.

15. Sredniy kvadrat dipol'nogo momenta makromolekuly kak funkciya uporyadochennosti ee monomernyh edinic / N.N. Matveev, V.I. Lisicyn, V.V. Saushkin, N.S. Kamalova // Plasticheskie massy. - 2021. - № 9-10. - S. 30-33.

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